発表論文2008-2010


  1. H. Tamiaki, H. Yoshimura, Y. Shimamura, M. Kunieda, "Self-aggregation behavior of synthetic zinc 3-hydroxymethyl-13/15-carbonyl-chlorins as models of main light-harvesting components in photosynthetic green bacteria," Photosynth. Res., 95, 223–228 (2008).

  2. J. Harada, T. Mizoguchi, S. Yoshida, M. Isaji, H. Oh-oka, H. Tamiaki, "Composition of localization of bacteriochlorophyll a intermediates in the purple photosynthetic bacterium Rhodopseudomonas sp. Rits," Photosynth. Res., 95, 213–221 (2008).

  3. C. Yogi, K. Kojima, N. Wada, H.Tokumoto, T. Takai, T. Mizoguchi, H. Tamiaki, "Photocatalytic Degradation of Methylene Blue by TiO2 Film and Au Particles-TiO2 Composite Film," Thin Solid Films, 516, 5881–5884 (2008).

  4. K. Minamizaki, T. Mizoguchi, T. Goto, H. Tamiaki, Y. Fujita, "Identification of two homologous genes, chlAI and chlAII, that are differentially involved in isocyclic ring formation of chlorophyll a in the cyanobacterium Synechocystis sp. PCC 6803," J. Biol. Chem., 283, 2684–2692 (2008).

  5. Q.-M. Wang, K. Ogawa, K. Toma, H. Tamiaki, "A novel luminescent organogel containing dysprosium ions quenched by sol-gel transition," Chem. Lett., 37, 430-431 (2008).

  6. T. Mizoguchi, M. Isaji, J. Harada, H. Tamiaki, "Identification of 3,4-didehydrorhodopin as major carotenoid in Rhodopseudomonas species," Photochem. Photobiol. Sci., 7, 492–497 (2008).

  7. X.-F. Wang, Y. Koyama, H. Nagae, Y. Wada, S. Sasaki, H. Tamiaki, "Dependence of photocurrent and conversion efficiency of titania-based solar cell on the Qy absorption and one electron-oxidation potential of pheophorbide sensitizer," J. Phys. Chem., C, 112, 4418–4426 (2008).

  8. R. Shibata, K. Koike, H. Hori, H. Tamiaki, "Self-aggregation of Synthetic Zinc Chlorophyll Derivatives Possessing Fluoroalkyl Chains in Liquid Carbon Dioxide as Models of Green Photosynthetic Bacterial Antennae," Chem. Lett., 37, 532–533 (2008).

  9. H. Tamiaki, K. Hamada, M. Kunieda, "Synthesis of 3/8-carbonylated chlorophyll derivatives and regiodependent reductivity of their carbonyl substituents," Tetrahedron, 64, 5721–5727 (2008).

  10. S. Sasaki, K. Mizutani, M. Kunieda, H. Tamiaki, "Synthesis, modification, and optical properties of C3-ethynylated chlorophyll derivatives," Tetrahedron Lett., 49, 4113–4115 (2008).

  11. T. Mizoguchi, M. Isaji, J. Harada, H. Tamiaki, "Compositional analysis of carotenoids in a purple photosynthetic bacteria, Rhodopseudomonas sp. strain Rits, upon irradiated light intensity," Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis (Ed by J. F. Allen, E. Gantt, J. H. Golbeck, B. Osmond), 273–277, Springer, Heidelberg (2008).

  12. Y. Saga, H. Kida, Y. Nishikawa, H. Tamiaki, "Chlorosomal self-aggregation of zinc chlorophyll derivatives in the presence of cationic surfactant cetyltrimethylammonium bromide and oraganosilanes in aqueous phase," Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis (Ed by J. F. Allen, E. Gantt, J. H. Golbeck, B. Osmond), 315–318, Springer, Heidelberg (2008).

  13. T. Mizoguchi, J. Harada, S. Yoshida, M. Isaji, H. Tamiaki, "Diversity and localization of bacteriochlorophylls possessing different 17-propionate groups in purple bacterial antennae," Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis (Ed by J. F. Allen, E. Gantt, J. H. Golbeck, B. Osmond), 327–330, Springer, Heidelberg (2008).

  14. H. Tamiaki, H. Sumi, "Chiral self-assembly of synthetic zinc protobacteriochlorophyll-d derivatives," Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis (Ed by J. F. Allen, E. Gantt, J. H. Golbeck, B. Osmond), 335–337, Springer, Heidelberg (2008).

  15. H. Tamiaki, T. Michitsuji, R. Shibata, "Synthesis of zinc bacteriochlorophyll-d analogues with various 17-substituents and their chlorosomal self-aggregates in non-polar organic solvents," Photochem. Photobiol. Sci., 7, 1225–1237 (2008).

  16. H. Tamiaki, K. Fukai, H. Shimazu, K. Nishide, Y. Shibata, S. Itoh, M. Kunieda, "Covalently linked zinc chlorophyll dimers as a model of the chlorophyllous pair in photosynthetic reaction centers," Photochem. Photobiol. Sci., 7, 1231–1237 (2008).

  17. J. Harada, S. Miyago, T. Mizoguchi, C. Azai, K. Inoue, H. Tamiaki, H. Oh-oka, "Accumulation of chlorophyllous pigments esterified with geranylgeranyl group and photosynthetic competence in the CT2256-deleted mutant of the green sulfur bacterium Chlorobium tepidum," Photochem. Photobiol. Sci., 7, 1179–1187 (2008).

  18. Y. Saga, J. Harada, H. Hattori, K. Kaihara, Y. Hirai, H. Oh-oka, H. Tamiaki, "Spectroscopic properties and bacteriochlorophyll c isomer composition of extramembranous light-harvesting complexes in the green sulfur photosynthetic bacterium Chlorobium tepidum and CT0388-deleted mutant under vitamin B12-limited conditions," Photochem. Photobiol. Sci., 7, 1210–1215 (2008).

  19. H. Tamiaki, K. Mizutani, M. Kunieda, S. Sasaki, "Synthesis of C3-substituted chlorophyll derivatives by modification of ethynyl group at the 3-position," J. Porphyrins Phthalocyanines, 12, 641 (2008).

  20. H. Tamiaki, K. Mizutani, M. Kunieda, S. Sasaki, "Synthesis and optical property of 3-ethynylated chlorophyll derivaitive," J. Porphyrins Phthalocyanines, 12, 642 (2008).

  21. M. Kunieda, H. Tamiaki, "Synthesis of zinc 3-hydroxymethyl-porphyrins possessing carbonyl groups at the 13- and/or 15-positions for models of self-aggregative chlorophylls in green photosynthetic bacteria," J. Org. Chem., 73, 7686–7694 (2008).

  22. H. Tamiaki, Y. Kotegawa, K. Mizutani, "Rotational deviation of 3-acetyl group from cyclic tetrapyrrole p-plane in synthetic bacteriochlorophyll-a analogs by 20-substitution," Bioorg. Med. Chem. Lett., 18, 6037–6040 (2008).

  23. T. Mizoguchi, T.-Y. Kim, S. Sawamura, H. Tamiaki, "Pressure-induced red shift and broadening of the Qy absorption of main light-harvesting antennae chlorosomes from green photosynthetic bacteria and their dependency upon alkyl substituents of the composite bacteriochlorophylls," J. Phys. Chem., B, 112, 16759–16765 (2008).

  24. T. Mizoguchi, J. Harada, M. Isaji, S. Yoshida, H. Oh-oka, H. Tamiaki, "Preferential binding of hydroxy-carotenoids to the peripheral antenna and methoxy-analogs to the core complexes in the purple photosynthetic bacterium Rhodopseudomonas sp. Rits," Car. Sci., 13, 33–37 (2008).

  25. H. Tamiaki, Y. Kotegawa, S. Nitta, S. Sasaki, K. Mizutani, "Synthesis of 32-substituted bacteriochlorophyll-d analogs and their self-aggregation in a nonpolar organic solvent," Tetrahedron, 65, 628–637 (2009).

  26. H. Morishita, H. Tamiaki, "Specific coupling between the 13-keto carbonyl and chlorin skeletal vibrational modes of synthetic 131-18O-(un)labeled metallochlorophyll derivatives," Spectrochimica Acta A, 72, 274–279 (2009).

  27. Q.-M. Wang, K. Ogawa, K. Toma, H. Tamiaki, "Smart pH sensitive luminescence hydrogel based on Eu(III) b-diketonate complex and its enhanced photostability," J. Photochem. Photobiol., A: Chem., 201, 87–90 (2009).

  28. Y. Ohya, N. Hashimoto, S. Jo, T. Nohori, T. Yoshikuni, T. Ouchi, H. Tamiaki, "Synthesis of Oligo-DNA Containing Hydrophilic Porphyrin On the Main Chain, and Its Energy Transfer Behavior in Duplex State," Supramol. Chem., 21, 301-309 (2009).

  29. S. Sasaki, Y. Kotegawa, H. Tamiaki, "Chlorophyll- and bacteriochlorophyll-derived colorimetric chemosensors for amine detection," Bull. Chem. Soc. Jpn., 82, 267–271 (2009).

  30. T. Mizoguchi, M. Isaji, J. Harada, K. Watabe, H. Tamiaki, "Structural determination of the D2,10-phytadienyl substituent in the 17-propionate of bacteriochlorophyll-b from Halorhodospira halochloris," J. Porphyrins Phthalocyanines, 13, 41–50 (2009).

  31. H. Tamiaki, A. Shinkai, Y. Kataoka, "Synthesis of galactosylated zinc bacteriochlorophyll-d analogs and their self-aggregation in an aqueous methanol solution," J. Photochem. Photobiol., A: Chem., 207, 113–123 (2009).

  32. Y. Saga, Y. Nakai, H. Tamiaki, "Temperature-dependent spectral changes of self-aggregates of zinc chlorophylls esterified by different linear alcohols at the 17-propionate," Supramol. Chem., 21, 738–746 (2009).

  33. X.-F. Wang, O. Kitao, H. Zhou, H. Tamiaki, S. Sasaki, "Extension of p-conjugation length along the Qy axis of a chlorophyll a derivative for efficient dye-sensitized solar cells," Chem. Commun., 1523–1525 (2009).

  34. X.-F. Wang, O. Kitao, H. Zhou, H. Tamiaki, S. Sasaki, "Efficient Dye-Sensitized Solar Cell Based on Oxo-Bacteriochlorin Sensitizers with Broadband Absorption Capability," J. Phys. Chem. C, 113, 7954–7961 (2009).

  35. T. Mizoguchi, C. Nagai, M. Kunieda, Y. Kimura, A. Okamura, H. Tamiaki, "Stereochemical Determination of the Unique Acrylate Moiety at the 17-Position in Chlorophylls-c from a Diatom Chaetoseros calcitrans and Its Effect upon Electronic Absorption Properties," Org. Biomol. Chem., 7, 2120–2126 (2009). [selected as the inside front cover of issue 10]

  36. Y. Shibata, Y. Saga, H. Tamiaki, S. Itoh, "Anisotropic Distribution of Emitting Transition Dipoles in Chlorosome from Chlorobium tepidum: Fluorescence Polarization Anisotropy Study of Single Chlorosomes," Photosynth. Res., 100, 67–78 (2009).

  37. Y. Hirai, H. Tamiaki, S. Kashimura, Y. Saga, "Physicochemical Studies of Demetalation of Light-Harvesting Bacteriochlorophyll Isomers Purified from Green Sulfur Photosynthetic Bacteria," Photochem. Photobiol., 85, 1140–1146 (2009).

  38. Q.-M. Wang, S. Sasaki, H. Tamiaki, "Near-infrared luminescence from ytterbium (III) ternary complexes by visible-light excitation of attached chlorophyll derivatives," Chem. Lett., 38, 648–649 (2009).

  39. Q.-M. Wang, H. Tamiaki, "Highly Efficient and Selective Turn-Off Quenching of Ligand-Sensitized Luminescence From Europium Imidazo[4,5-f]-1,10-phenanthroline Complex by Fluoride Ion," J. Photochem. Photobiol., A: Chem., 206, 124–128 (2009).

  40. S. Sasaki, Y. Kotegawa, K. Azuma, M. Kunieda, H. Tamiaki, "Chlorophyll-Derived Thermochromic Sensor Based on α-Amino Alcohol Adduct Formation via Reversible Intramolecular Cyclization," Chem. Lett., 38, 796–797 (2009).

  41. Y. Saga, T. Nakagawa, T. Miyatake, H. Tamiaki, "Change of Aqueous Self-Assemblies of Zinc Chlorophyll Derivatives Possessing a Hydrophilic Chain by Treatments with Organic Solvents," Chem. Lett., 38, 882–883 (2009).

  42. M. Kunieda, H. Tamiaki, "Synthesis of regioisomeric bacteriochlorophyll-d analogues possessing a hydroxy group at the 21- or 31-position. Their chlorosome-like self-aggregation in solid films," J. Org. Chem., 74, 5803–5809 (2009). [selected as a Featured Article]

  43. T. S. Balaban, A. D. Bhise, G. Bringmann, J. Bürck, C. Chappaz-Gillot, A. Eichhöfer, D. Fenske, T. Mizoguchi, D. Mössinger, M. Reichert, H. Rösner, C. Roussel, M. Schraut, H. Tamiaki, N. Vanthuyne, "Mimics of the self-assembling chlorosomal bacteriochlorophylls: Regioselective diacylations of porphyrins, subsequent stereoselective monoreduction to acyl-hydroxyalkyl-porphyrins and the assignment of their absolute configurations," J. Am. Chem. Soc., 131, 14480–14492 (2009).

  44. M. Kunieda, H. Tamiaki, "Self-aggregation of synthetic bacteriochlorophyll-d analogues possessing a B-ring reduced chlorin π-system," J. Org. Chem., 74, 8437–8440 (2009).

  45. Y. Hirai, H. Tamiaki, S. Kashimura, Y. Saga, "Demetalation Kinetics of Natural Chlorophylls Purified from Oxygenic Photosynthetic Organisms: Effect of the Formyl Groups Conjugated Directly to the Chlorin π-Macrocycle," Photochem. Photobiol. Sci., 8, 1701–1707 (2009).

  46. M. Numata, K. Kaneko, H. Tamiaki, S. Shinkai, ""Supramolecular" Amphiphiles Created by Wrapping of Poly(styrene) with Helix-Formation β-1,3-Glucan Polysaccharide," Chem. Eur. J., 15, 12338–12345 (2009).

  47. Y. Saga, H. Tamiaki, "Photofunctional nanodevices mimicking light-harvesting complexes of green photosynthetic bacteria," Encyclopedia of Nanoscience and Nanotechnology, in press (2010).

  48. T. Mizoguchi, Y. Kimura, H. Tamiaki, "Exclusive observation of the (132R)-enantiomer of chlorophyll-c from a diatom Chaetoseros calcitrans," Photochem. Photobiol., 86, 311–315 (2010).

  49. X.-F. Wang, H. Tamiaki, "Cyclic tetrapyrrole based molecules for dye-sensitized solar cells," Energy Environ. Sci., 3, 94–106 (2010).

  50. H. Tamiaki, T. Kozawa, R. Kitamoto, M. Kunieda, "Synthesis of meso-tetraarylporphyrins possessing amino and carboxy groups and their peptides," J. Porphyrins Phthalocyanines, 14, 375–388 (2010).

  51. H. Tamiaki, S. Tateishi, S. Nakabayashi, Y. Shibata, S. Itoh, "Linearly polarized light absorption spectra of chlorosomes, light-harvesting antennas of photosynthetic green sulfur bacteria," Chem. Phys. Lett., 484, 333–337 (2010).

  52. Y. Saga, Y. Shibata, H. Tamiaki, "Spectral properties of single light-harvesting complexes in bacterial photosynthesis," J. Photochem. Photobiol., C: Photochem. Rev., 11, 15–24 (2010).

  53. M. Kunieda, H. Tamiaki, "Self-aggregation of synthetic multi-hydroxylated zinc chlorophylls," Tetrahedron, 66, 1228–1235 (2010).

  54. T. Miyatake, H. Tamiaki, "Self-Aggregates of Natural Chlorophylls and Their Synthetic Analogues in Aqueous Media for Making Light-Harvesting Systems," Coord. Chem. Rev., 254, 2593–2602 (2010).

  55. H. Tamiaki, K. Ogawa, K. Enomoto, K. Taki, A. Hotta, K. Toma, "Supramolecular gelation of alcohols and water by synthetic amphiphilic gallic acid derivatives," Tetrahedron, 66, 1661–1666 (2010).

  56. X.-F. Wang, O. Kitao, E. Hosono, H. Zhou, S. Sasaki, H. Tamiaki, "TiO2- and ZnO-Based Solar Cells Using a Chlorophyll a Derivative Sensitizer for Light-Harvesting and Energy Conversion," J. Photochem. Photobiol. A: Chem., 210, 145–152 (2010)

  57. X.-F. Wang, Y. Koyama, O. Kitao, Y. Wada, S. Sasaki, H. Tamiaki, H. Zhou, "Significant enhancement in the power-conversion efficiency of chlorophyll co-sensitized solar cells by mimicking the principles of natural photosynthetic light-harvesting complexes," Biosensors Bioelectronics, 25, 1970–1976 (2010).

  58. N. Muraki, J. Nomata, K. Ebata, T. Mizoguchi, T. Shiba, H. Tamiaki, G. Kurisu, Y. Fujita, "X-ray crystal structure of the light-independent protochlorophyllide reductase," Nature, 465, 110–114 (2010).

  59. X.-F. Wang, H. Tamiaki, O. Kitao, H. Zhou, S. Sasaki, "Chlorophyll-a derivatives with various hydrocarbon ester groups for efficient dye-sensitized solar cells," Langmuir, 26, 6320–6327 (2010).

  60. H. Tamiaki, M. Kunieda, "Photochemistry of chlorophylls and their synthetic analogs," Handbook of Porphyrin Science, 11, 223–290 (2010).

  61. M. Kunieda, H. Tamiaki, "J-Aggregation of Zinc 31,131-Dihydroxy-Chlorins by Exclusive Coordination Bonding Between 31-Hydroxy Group and Central Zinc Atom," Chem. Lett., 39, 640–642 (2010).

  62. Q.-M. Wang, C. Tan, H. Tamiaki, H. Chen, "Emission Response towards Three Anions (F-, HSO4- and AcO-) by a Luminescent Europium Ternary Complex with a 2-Arylimidazole-1,10-phenanthroline Conjugate," Photochem. Photobiol. Sci., 9, 791–795 (2010).

  63. S. Sasaki, M. Yoshizato, M. Kunieda, H. Tamiaki, "Cooperative C3- and C13-Substituent Effects on Synthetic Chlorophyll Derivatives," Eur. J. Org. Chem., 5287–5291 (2010).

  64. J. Wen, J. Harada, K. Buyle, K. Yuan, H. Tamiaki, H. Oh-oka, R. A. Loomis, R. E. Blankenship, "Characterization of an FMO protein variant of Chlorobaculum tepidum carrying bacteriochlorophyll a esterified by geranylgeraniol," Biochemistry, 49, 5455–5463 (2010).

  65. Y. Kataoka, Y. Shibata, H. Tamiaki, "Intramolecular Excitation Energy Transfer from Visible-Light Absorbing Chlorophyll Derivatives to a Near-Infrared-Light Emitting Boron Dipyrromethene Moiety," Chem. Lett., 39, 953–955 (2010).

  66. K. Takano, S. Sasaki, D. Citterio, H. Tamiaki, K. Suzuki, "An Oxo-Bacteriochlorin Derivative for Long-Wavelength Fluorescence Ratiometric Alcohol Sensing," Analyst, 135, 2334–2339 (2010).

  67. Q.-M. Wang, C. Tan, H. Chen, H. Tamiaki, "A New Fluoride Luminescence Quencher Based on a Nanostructures Covalently Bonded Terbium Hybrid Material," J. Phys. Chem. C, 114, 13879–13883 (2010).

  68. Y. Shibata, S. Tateishi, S. Nakabayashi, S. Itoh, H. Tamiaki, "Intensity borrowing via excitonic couplings among Soret and Qy transitions of bacteriochlorophylls in the pigment aggregates of chlorosomes, the light-harvesting antennae of green sulfur bacteria," Biochemsitry, 49, 7504–7515 (2010).

  69. H. Morishita, T. Mizoguchi, H. Tamiaki, "Synthesis of 18O-labelled photosynthetically active chlorophylls at the 3- or 7-carbonyl group with high regioselectivity," Photosynth. Res., 105, 257–263 (2010).

  70. M. Sugishima, Y. Okamoto, M. Noguchi, T. Kohchi, H. Tamiaki, K. Fukuyama, "Crystal structures of the substrate-bound forms of red chlorophyll catabolite reductase: the implications for the site- and stereospecific reaction," J. Mol. Biol., 402, 937–949 (2010).

  71. H. Tamiaki, H. Morishita, "Vibrational analysis of self-aggregates of synthteic zinc and cadmium 131-18O-labelled bacteriochlorophyll-d analogs," Bull. Chem. Soc. Jpn., 83, 1548–1550 (2010).


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