発表論文2011-2013


  1. Q.-M. Wang, K. Ogawa, Y. Li, H. Tamiaki, "Efficient photosensitization of terbium ions enabled by hydrolysis of siloxy groups in ligands with specific side-chains," Photochem. Photobiol. Sci., 10, 60–65 (2011).

  2. Q.-M. Wang, Y. Li, H. Tamiaki, "Study of Interactions Between Eu(thenoyltrifluoroacetonate)3 and a Photosynthetic Chlorophyllous Pigment," J. Sol. Chem., 40, 320–326 (2011).

  3. H. Tamiaki, D. Takekoshi, T. Mizoguchi, "Reduction of vinyl groups in naturally occurring chlorophylls-a," Bioorg. Med. Chem., 19, 52–57 (2011).

  4. H. Tamiaki, J. Komada, M. Kunieda, K. Fukai, T. Yoshitomi, J. Harada, T. Mizoguchi, "In vitro synthesis and characterization of bacteriochlorophyll-f and its absence in bacteriochlorophyll-e producing organisms," Photosynth. Res., 107, 133–138 (2011).

  5. T. Yoshitomi, T. Mizoguchi, M. Kunieda, H. Tamiaki, "Characterization of Glycolipids in Light-Harvesting Chlorosomes from the Green Photosynthetic Bacterium Chlorobium tepidum," Bull. Chem. Soc. Jpn., 84, 395–402  (2011).

  6. Y. Hirai, S. Sasaki, H. Tamiaki, S. Kashimura, Y. Saga, "Substitution Effects in the A- and B-Rings of the Chlorin Macrocycle on Demetalation Properties of Zinc Chlorophyll Derivatives," J. Phys. Chem. B., 115, 3240–3244 (2011).

  7. T. Oba, Y. Uda, K. Matsuda, T. Fukusumi, S. Ito, K. Hiratani, H. Tamiaki, "A mild conversion from 3-vinyl- to 3-formyl-chlorophyll derivatives," Bioorg. Med. Chem. Lett., 21, 2489–2491 (2011).

  8. Y. Okamoto, H. Tamiaki, "C3- and C13-Substituent effect on electronic absorption spectra of linear tetrapyrroles produced by photooxidation of zinc chlorophyll derivatives," J. Photochem. Photobiol. A: Chem., 219, 250–254 (2011).

  9. H. Tamiaki, M. Kunieda, "Photochemistry of chlorophylls and their synthetic analogs," Handbook of Porphyrin Science, 11, 223–290 (2011).

  10. T. Mizoguchi, T. Yoshitomi, J. Harada, H. Tamiaki, "Temperature- and time-dependent changes in the structure and composition of glycolipids during the growth of the green sulfur photosynthetic bacterium Chlorobaculum tepidum," Biochemistry, 50, 4504–4512 (2011).

  11. S. Sasaki, K. Mizutani, M. Kunieda, H. Tamiaki, "Synthesis and optical properties of C3-ethynylated chlorin and p-extended chlorophyll dyads," Tetrahedron, 67, 6065–6072 (2011).

  12. S. Masuda, J. Harada, M. Yokono, Y. Yuzawa, M. Shimojima, K. Murofushi, H. Tanaka, H. Masuda, M. Murakawa, T. Haraguchi, M. Kondo, M. Nishimura, H. Yuasa, M. Noguchi, H. Oh-oka, A. Tanaka, H. Tamiaki, and H. Ohta, "A monogalactosyldiacylglycerol synthase found in green sulfur bacterium Chlorobaculum tepidum reveals important roles for galactolipids in photosynthesis," Plant Cell, 23, 2644–2658 (2011).

  13. Y. Saga, H. Tamiaki, "Photofunctional nanodevices mimicking light-harvesting complexes of green photosynthetic bacteria," Encyclopedia of Nanoscience and Nanotechnology, 20, 513–521 (2011).

  14. T. Mizoguchi, Y. Kimura, T. Yoshitomi, H. Tamiaki, "The stereochemistry of chlorophyll-c2 from the haptophyte Emiliania huxleyi: the (132R)-enantiomers of chlorophylls-c are exclusively selected as the photosynthetically active pigments in chromophyte algae," Biochim. Biophys. Acta, 1807, 1467–1473 (2011).

  15. R. Nishimori, T. Mizoguchi, H. Tamiaki, S. Kashimura, Y. Saga, "Biosynthesis of unnatural bacteriochlorophyll c derivatives esterified with a,w-diols in the green sulfur photosynthetic bacterium Chlorobaculum tepidum," Biochemistry, 50, 7756–7764 (2011).

  16. X.-F. Wang, L.Wang, N. Tamai, O. Kitao, H. Tamiaki, S. Sasaki, "Development of Solar Cells Based on Synthetic Near Infrared Absorbing Purpurins: Observation of Multiple Electron Injection Pathways at Cyclic Tetrapyrrole-Semiconductor Interface," J. Phys. Chem. C, 115, 24394–24402 (2011).

  17. H. Tamiaki, H. Takebe, S. Sasaki, Y. Kataoka, "Synthesis of oligomethylene-strapped chlorophyll derivatives and optical properties of their stereoisomers in a solution," Photosynth. Res., 111, 1–8 (2012).

  18. G. Pattanayak, S. Venkataramani, S. Hörtensteiner, L. Kunz, B. Christ, M. Moulin, A. G. Smith, Y. Okamoto, H. Tamiaki, M. Sugishima, J. Greenberg, "ACCELERATED CELL DEATH 2 suppresses mitochondrial oxidative bursts and modulates cell death in Arabidopsis," Plant J., 69, 589–600  (2012).

  19. H. Tamiaki, Y. Okamoto, Y. Mikata, S. Shoji, "Photooxidative cleavage of zinc 20-substituted chlorophyll derivatives: conformationally P-helix–favored formation of regioselectively 19–20 opened linear tetrapyrroles," Photochem. Photobiol. Sci., 11, 898–907 (2012).

  20. M. Numata, D. Kinoshita, N. Taniguchi, H. Tamiaki, A. Ohta, "Self-assembly of amphiphilic molecules in droplet compartments: discrete sub-micrometer-sized one-dimensional structures," Angew. Chem. Int. Ed., 51, 1844–1848 (2012).

  21. T. Mizoguchi, M. Isaji, J. Harada, H. Tamiaki, "Isolation and pigment composition of the reaction centers from purple photosynthetic bacterium Rhodopseudomonas palustris species," Biochim. Biophys. Acta, 1817, 395–400 (2012).

  22. T. Tsuchiya, T. Mizoguchi, S. Akimoto, T. Tomo, H. Tamiaki, M. Mimuro, "Metabolic engineering of the chlorophyll d-dominated cyanobacterium Acaryochloris marina: production of a novel chlorophyll species by the introduction of the chlorophyllide a oxygenase gene," Plant Cell Physiol., 53, 518–527 (2012).

  23. T. Tsuchiya, S. Akimoto, T. Mizoguchi, K. Watabe, H. Kindo, T. Tomo, H. Tamiaki, M. Mimuro, "Artificial produced [7-formyl]-chlorophyll d functions as an antenna pigment in the photosystem II isolated from the chlorophyllide a oxygenase-expressing Acaryochloris marina," Biochim. Biophys. Acta, 1817, 1285–1291 (2012).

  24. A. Jesorka, A. R. Holzwarth, A. Eichhöfer, C. M. Reddy, Y. Kinoshita, H. Tamiaki, M. Katterle, J.-V. Naubron, T. S. Balaban, "Water Coordinated Zinc Dioxo-Chlorin and Porphyrin Self-assemblies as Chlorosomal Mimics: Variability of the Supramolecular Interactions," Photochem. Photobiol. Sci., 11, 1069–1080 (2012).

  25. H. Tamiaki, M. Xu, T. Mizoguchi, "Photoreduction of zinc 3-acetyl-chlorophyll derivative to prepare chemically stable isobacteriochlorin," Tetrahedron Lett., 53, 3210–3212 (2012).

  26. H. Tamiaki, S. Machida, K. Mizutani, "Modification of 3-substituents in (bacterio)chlorophyll derivatives to prepare 3-ethylated, methylated and unsubstituted (nickel) pyropheophorbides and their optical properties," J. Org. Chem., 77, 4751–4758 (2012).

  27. T. Fukusumi, K. Matsuda, T. Mizoguchi, T. Miyatake, S. Ito, T. Ikeda, H. Tamiaki, T. Oba, "Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: a model oxidation pathway for chlorophyll-d biosynthesis," FEBS Lett., 586, 2338–2341 (2012).

  28. N. Takahashi, S. Shoji, H. Tamiaki, Y. Saga, "Self-assembly of zinc bacteriochlorophyll d derivatives possessing a triethoxysilyl group at the 17-propionate residue," Bull. Chem. Soc. Jpn., 85, 989–994 (2012).

  29. H. Tamiaki, M. Xu, S. Machida, "Photoreduced deformylation of zinc chlorophyll-d derivative," Chem. Lett., 41, 820–821 (2012).

  30. Y. Saga, H. Tamiaki, "Demetalation of Chlorophyll Pigments," Chem. Biodiv., 9, 1659–1683 (2012).

  31. S. Sasaki, K. Mizutani, M. Kunieda, H. Tamiaki, "Construction of chlorophyll assemblies based on zinc complexes of triazole-chlorin conjugates," Tetrahedron, 68, 7133–7139 (2012).

  32. Y. Kataoka, Y. Shibata, H. Tamiaki, "Supramolecular Energy Transfer form Photoexcited Chlorosomal Zinc Porphyrin Self-Aggregates to a Chlorin or Bacteriochlorin Monomer as Models of Main Light-Harvesting Antenna Systems in Green Photosynthetic Bacteria," Bioorg. Med. Chem. Lett., 22, 5218–5221 (2012).

  33. S. Shoji, T. Hashishin, H. Tamiaki, "Construction of chlorosomal rod self-aggregates in the solid state on any substrates from synthetic chlorophyll derivatives possessing an oligomethylene chain at the 17-propionate residue," Chem. Eur. J., 18, 13331–13341 (2012). [Back cover]

  34. Y. Kashiyama, A. Yokoyama, Y. Kinoshita, S. Shoji, H. Miyashita, T. Shiratori, H. Suga, K. Ishikawa, I. Inouye, K. Ishida, D. Fujinuma, K. Aoki, M. Kobayashi, S. Nomoto, T. Mizoguchi, H. Tamiaki, "Ubiquity and Quantitative Significance of Chlorophyll Detoxification Catabolism Associated with Protistan Herbivory in Aqueous Ecosystems," Proc. Natl. Acad. Sci., USA, 109, 17328–17335 (2012). [Feature Article, Front cover]

  35. J. Harada, T. Mizoguchi, Y. Tsukatani, M. Noguchi, H. Tamiaki, "A seventh bacterial chlorophyll driving a large light-harvesting antenna," Scientific Reports, 2, 671; DOI:10.1038/srep00671 (2012).20129月注目の論文]

  36. S. Machida, Y. Isoda, M. Kunieda, H. Tamiaki, "Synthesis and epoxide-opening reaction a 3-oxiranyl-chlorophyll derivative," Tetrahedron Lett., 53, 6277–6279 (2012).

  37. Y.-W. Wang, X.-F. Wang, J.-P. Zhang, Z. Hong, J. Kido, O. Kitao, T. Ikeuchi, H. Tamiaki, S. Sasaki, "Development of solar cells based on synthetic near-infrared absorbing purpurins 2: Use of fullerene and its derivatives as electron acceptors for favorable charge separation," J. Phys. Chem. C., 116, 21244–21254 (2012).

  38. T. Mizoguchi, J. Harada, H. Tamiaki, "Characterization of chlorophyll pigments in the mutant lacking 8-vinyl reductase of green photosynthetic bacterium Chlorobaculum tepidum," Bioorg. Med. Chem., 20, 6803–6810 (2012).

  39. M. Numata, M. Takayama, S. Shoji, H. Tamiaki, "Microflow-driven temporal self-assembly of amphiphilic molecules," Chem. Lett., 41, 1689–1691 (2012).

  40. H. Tamiaki, N. Kosaka, Y. Kinoshita, "Metallation of a cyclic chlorophyll hetero-dyad and optical properties of synthetic metallo-dyads," Res. Chem. Int., 39, 221–232 (2013).

  41. H. Tamiaki, M. Xu, Y. Kinoshita, "Synthesis of oxo-, thioxo- and methylene-substituted bacteriochlorins by modifying chlorophyll-a and their electronic absorption in visible and near-infrared regions," J. Photochem. Photobiol. A: Chem., 252, 60–68 (2013).

  42. Y. Saga, Y. Hirai, K. Sadaoka, M. Isaji, H. Tamiaki, "Structure-dependent demetalation kinetics of chlorophyll a analogs under acidic conditions," Photochem. Photobiol., 89, 68–73 (2013).

  43. M. Numata, D. Kinoshita, N. Hirose, T. Kozawa, H. Tamiaki, Y. Kikkawa, M. Kanesato, "Controlled stacking and unstacking of peripheral chlorophyll units drives the spring-like contraction and expansion of a semi-artificial helical polymer," Chem. Eur. J., 53, 1592–1598 (2013).

  44. M. Numata, D. Kinoshita, N. Hirose, T. Kozawa, H. Tamiaki, "Orthogonal polymer recognition based on semi-artificial helical polysaccharide," Chem. Lett., 42, 266–268 (2013).

  45. Y. Kinoshita, M. Kunieda, Y. Mikata, H. Tamiaki, "Synthesis, crystal structure and electronic absorption of chlorophyll derivatives possessing a β-diketonate moiety at the C3 position," Tetrahedron Lett., 54, 1243–1246 (2013).

  46. H. Tamiaki, K. Azuma, Y. Kinoshita, R. Monobe, T. Miyatake, S. Sasaki, "Chemosensitive chlorophyll derivatives: optical detection of various amines by synthetic 3-trifluoroacetyl-131-deoxo-pyropheophorbides in solution," Tetrahedron, 69, 1987–1993 (2013).

  47. Y. Tsukatani, H. Yamamoto, J. Harada, T. Yoshitomi, J. Nomata, M. Kasahara, T. Mizoguchi, Y. Fujita, H. Tamiaki, "An unexpectedly branched biosynthetic pathway for bacteriochlorophyll b capable of absorbing near-infrared light," Scientific Reports, 3, 1217; DOI:10.1038/srep01217 (2013).

  48. T. Mizoguchi, J. Harada, T. Yoshitomi, H. Tamiaki, "A variety of glycolipids in green photosynthetic bacteria," Photosynth. Res., 114, 179–188 (2013).

  49. H. Tamiaki, M. Xu, T. Tanaka, T. Mizoguchi, "Photoreduction of zinc 8-vinylated chlorophyll derivative to bacteriochlorophyll-b/g analog possessing an 8-ethylidene group" Bioorg. Med. Chem. Lett., 23, 2377–2379 (2013).

  50. J. Harada, T. Mizoguchi, S. Satoh, Y. Tsukatani, M. Yokono, M. Noguchi, A. Tanaka, H. Tamiaki, "Specific gene bciD for C7-methyl oxidation in bacteriochlorophyll e biosynthesis of brown-colored green sulfur bacteria," PLoS ONE, 8(4), e60026. doi:10.1371/journal.0060026 (2013).

  51. N. Takahashi, H. Tamiaki, Y. Saga, "Synthesis and self-assembly of amphiphilic zinc chlorophyll derivatives possessing a crown ether at the 17-propionate residue," Tetrahedron, 69, 3638–3645 (2013).

  52. Y.-W. Wang, S. Sasaki, H. Tamiaki, J.-P. Zhang, T. Ikeuchi, Z. Hong, J. Kido, X.-F. Wang, "Dicyano-functionalized chlorophyll derivatives with ambipolar characteristic for organic photovoltaics," Organic Electronics, 14, 1972–1979 (2013).

  53. T. Mizoguchi, Y. Tsukatani, J. Harada, S. Takasaki, T. Yoshitomi, H. Tamiaki, "Cyclopropane-ring formation in the acyl group of chlorosomal glycolipids is crucial for acid resistance of green bacterial antenna systems," Bioorg. Med. Chem., 21, 3689–3694 (2013).

  54. H. Tamiaki, R. Monobe, S. Koizumi, T. Miyatake, Y. Kinoshita, "Stereoselective reduction, methylation and phenylation of the 13-carbonyl group in chlorophyll derivatives," Tetrahedron Asym., 24, 677–682 (2013).; erratum, 966, 967–972.

  55. X.-F. Wang, H. Tamiaki, O. Kitao, T. Ikeuchi, S. Sasaki, "Molecular engineering on a chlorophyll derivative, chlorin e6, for significantly improved efficiency in dye-sensitized solar cells," J. Power Sources, 242, 860–864 (2013).

  56. K. Sadaoka, T. Oba, H. Tamiaki, S. Kashimura, Y. Saga, "Pheophytinization kinetics of the zinc chlorophyll derivative possessing two formyl groups: effects of formyl groups conjugated to the chlorin macrocycle on physicochemical properties of photosynthetic pigments," J. Porphyr. Phthalocy., 17, 1120–1128 (2013).

  57. S. Shoji, T. Mizoguchi, H. Tamiaki, "Reconstruction of rod self-aggregates of natural bacteriochlorophyll-c from Chloroflexus aurantiacus," Chem. Phys. Lett., 578, 102–105 (2013).

  58. Y. Tsukatani, H. Yamamoto, T. Mizoguchi, Y. Fujita, H. Tamiaki, "Completion of biosynthetic pathways for bacteriochlorophyll g in Heliobacterium modesticaldum: The C8-ethylidene group formation," Biochim. Biophys. Acta, 1827, 1200–1204 (2013).

  59. Y. Kashiyama, A. Yokoyama, T. Shiratori, I. Inouye, Y. Kinoshita, T. Mizoguchi, H. Tamiaki, "132,173-Cyclopheophorbide b enol as a catabolite of chlorophyll b in phycophagy by protists," FEBS Lett., 587, 2578–2583 (2013).

  60. S. Sasaki, K. Mizutani, M. Kunieda, K. Azuma, H. Tamiaki, "Synthesis of chlorophyll derivatives directly connecting amino-derived functional groups at the C3-position," Chem. Lett., 42, 1212–1213 (2013).

  61. H. Tamiaki, N. Ariki , H. Sugiyama, Y. Taira, Y. Kinoshita, T. Miyatake, "Synthesis of 3,20-disubstituted chlorophyll-a derivatives and reactivity of the substituents," Tetrahedron, 69, 8412–8421 (2013).

  62. Y. Kinoshita, Y. Yamamoto, H. Tamiaki, "Synthesis, structure, and optical and redox properties of chlorophyll derivatives directly coordinating ruthenium bispyridine at the peripheral β-diketonate moiety," Inorg. Chem., 52, 9275–9283 (2013).

  63. S. Sasaki, K. Mizutani, M. Kunieda, H. Tamiaki, "Cycloaddition of C3-ethynylated chlorophyll derivative and self-aggregation of zinc chlorin–pyrazole/triazole conjugates," Tetrahedron, 69, 9772–9778 (2013).

  64. K. Sadaoka, S. Shoji, Y. Tsukatani, T. Yoshitomi, H. Tamiaki, S. Kashimura, Y. Saga, "Pheophytinization kinetics of chlorophyll c under weakly acidic conditions: Effects of acrylic acid residue at the 17-position," Bioorg. Med. Chem., 21, 6915–6919 (2013).

  65. Y. Tsukatani, J. Harada, T. Mizoguchi, H. Tamiaki, "Bacteriochlorophyll homolog composition in the bchU mutants of green sulfur bacteria," Photochem. Photobiol. Sci., 12, 2195–2201 (2013).

  66. T. Fukusumi, N. Takei, Y. Tateno, T. Mizoguchi, S. Ito, T. Ikeda, H. Tamiaki, T. Oba, "Ene-thiol reaction of C3-vinylated chlorophyll derivatives in the presence of oxygen: synthesis of C3-formyl-chlorins under mild conditions," J. Porphyr. Phthalocy., 17, 1188–1195 (2013).


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